Article 8313

Title of the article

CHEMISTRY OF POLYMERS AS A BASIS
OF SOME TECHNOLOGIES AND SOLUTION OF ENVIRONMENTAL PROBLEMS 

Authors

Gol'dfeyn Mark Davidovich, Doctor of chemical sciences, professor, head of sub-department of environmental protection and safety, Saratov State University named after N. G. Chernyshevsky (83 Astrakhanskaya street, Saratov, Russia), GoldfeinMD@info.sgu.ru
Kozhevnikov Nikolay Vladimirovich, Doctor of chemical sciences, associate professor, professor, sub-department of environmental protection and safety, Saratov State University named after N. G. Chernyshevsky
(83 Astrakhanskaya street, Saratov, Russia), KozevnikovNV@info.sgu.ru 

Index UDK

542(952+978):628.34

Abstract

The paper deals with new kinetic regularities of polymerization of vinyl monomers in homophase and heterophase conditions in the presence of transitive metal salt additives, azonitriles, peroxides, stable nitroxyl radicals and anion-radicals, aromatic amines and nitroso- compounds, emulsifiers and solvents of various kinds. We studied the mechanism of the whole process, as well as elementary stages. The kinetic characteristics of these processes were determined. Scientific principles of regulating polymer synthesis processes were elaborated. It allows us to optimize some industrial technologies and solve most important problems of environment protection. 

Key words

polymerization, kinetics, mechanism, monomer, polymer, initiator, inhibitor, emulsifier, environment. 

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References

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